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21.
The relationship between differences in microwave humidity sounder(MHS)–channel biases which represent measured brightness temperatures and model-simulated brightness temperatures, and cloud ice water path(IWP) as well as the influence of the cloud liquid water path(LWP) on the relationship is examined. Seven years(2011–17) of NOAA-18 MHS-derived measured brightness temperatures and IWP/LWP data generated by the NOAA Comprehensive Large Array-data Stewardship System Microwave Surface and Precipitation Products System are used. The Community Radiative Transfer Model, version2.2.4, is used to simulate model-simulated brightness temperatures using European Center for Medium-Range Weather Forecasts reanalysis data as background fields. Scan-angle deviations of the MHS window channel biases range from-1.7 K to1.0 K. The relationships between channels 2, 4, and 5 biases and scan angle are symmetrical about the nadir. The latitudedependent deviations of MHS window channel biases are positive and range from 0–7 K. For MHS non-window channels,the latitudinal deviations between measured brightness temperatures and model-simulated brightness temperatures are larger when the detection height is higher. No systematic warm or cold deviations are found in the global spatial distribution of difference between measured brightness temperatures and model-simulated brightness temperatures over oceans after removing scan-angle and latitudinal deviations. The corrected biases of five different MHS channels decrease differently with respect to the increase in IWP. This decrease is stronger when LWP values are higher.  相似文献   
22.
满浩然  臧淑英  李苗  张鑫 《测绘科学》2021,46(3):124-132
针对无源微波遥感时间分辨率高可以克服云层影响获取地表温度的问题,该文应用AMSR-E微波亮度温度数据,分别选取了基于发射率估计的单通道反演法和多通道线性拟合法反演东北地区地表温度。在原有方法的基础上提出算法改进:对单通道反演法按照植被生长周期在生长季与非生长季分别建立发射率估计方程,探究各微波通道在每种地表覆被类型的反演能力并组合反演精度最高的通道,将微波极化差异指数作为表征发射率参数加入多通道拟合方程。结果显示,获取的地表温度剔除水体和冰雪无效像元后可用性达到100%,改进后的单通道反演法均方根误差由3.58~4.6降低至2.0~3.1,在75%的区域的误差小于2 K;多通道拟合法的最终均方根误差为2.6~3.5,同样有较高精度且只使用微波亮温数据就能获取地表温度。  相似文献   
23.
一维综合孔径微波辐射计能够有效提高观测的空间分辨率,其观测入射角通常在0°~55°范围内变化。为了开发适用于一维综合孔径微波辐射计的海面温度反演算法,需要评估其观测亮温对海洋大气环境要素的敏感性。利用海面发射率模型和大气辐射传输模型,构建了适用于一维综合孔径微波辐射计的微波海洋大气辐射传输模式,研究了C波段垂直和水平极化微波辐射亮温在不同入射角下对海洋大气环境要素的敏感性变化情况,并定量计算了相应的敏感系数。结果表明:垂直和水平极化亮温对海洋大气环境要素的敏感性表现出不同的特性。随着入射角的增大,垂直极化亮温对海面温度的敏感性增强,对海面风场的敏感性相对减弱;水平极化亮温则相反。由大气水汽含量和云液态水含量误差引入的垂直和水平极化亮温误差随入射角增大而增大,但是,即使在55°的大入射角下垂直和水平极化亮温误差仍小于0.12 K。对于海面温度反演精度优于1 K的要求,一维综合孔径微波辐射计的测温精度需优于0.6 K。研究结果对于一维综合孔径微波辐射计海面温度反演算法的研究和载荷设计具有一定的理论指导意义。  相似文献   
24.
The soil freeze–thaw controls the hydrological and carbon cycling and thus affects water and energy exchanges at land surface. This article reported a newly developed algorithm for distinguishing the freeze/thaw status of surface soil. The algorithm was based on information from Advanced Microwave Scanning Radiometer Enhanced (AMSR‐E) which records brightness temperature (Tb) in the afternoon and after midnight. The criteria and discriminant functions were obtained from both radiometer observations and model simulations. First of all, the microwave radiation from freeze–thaw soil was examined by carrying out experimental measurements at 18·7 and 36·5 GHz using a Truck‐mounted Multi‐frequency Microwave Radiometer (TMMR) in the Heihe River of China. The experimental results showed that the soil moisture is a key component that differentiates the microwave radiation behaviours during the freeze–thaw process, and the differences in soil temperature and emissivity between frozen and thawed soils were found to be the most important criteria. Secondly, a combined model was developed to consider the impacts of complex ground surface conditions on the discrimination. The model simulations quite followed the trend of in situ observations with an overall relation coefficient (R) of approximately 0·88. Finally, the ratio of Tb18·7H (horizontally polarized Tb at 18·7 GHz) to Tb36·5V was considered primarily as the quasi‐emissivity, which is more reasonable and explicit in measuring the microwave radiation changes in soil freezing and thawing than the spectral gradient. By combining Tb36·5V to indicate the soil temperature variety, a Fisher linear discrimination analysis was used to establish the discriminant functions. After being corrected by TMMR measurements, the new discriminant algorithm had an overall accuracy of 86% when validated by 4‐cm soil temperature. The multi‐year discriminant results also provided a good agreement with the classification map of frozen ground in China. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   
25.
Currently observed climate warming in the Arctic has numerous consequences. Of particular relevance, the precipitation regime is modified where mixed and liquid precipitation can occur during the winter season leading to rain‐on‐snow (ROS) events. This phenomenon is responsible for ice crust formation, which has a significant impact on ecosystems (such as biological, hydrological, ecological and physical processes). The spatially and temporally sporadic nature of ROS events makes the phenomenon difficult to monitor using meteorological observations. This paper focuses on the detection of ROS events using passive microwave (PMW) data from a modified brightness temperature (TB) gradient approach at 19 and 37 GHz. The approach presented here was developed empirically for observed ROS events with coincident ground‐based PMW measurements in Sherbrooke, Quebec, Canada. It was then tested in Nunavik, Quebec, with the Advanced Microwave Scanning Radiometer for the Earth Observing System (AMSR‐E). We obtained a detection accuracy of 57, 71 and 89% for ROS detection for three AMSR‐E grid cells with a maximum error of 7% when considering all omissions and commissions with regard to the total number of AMSR‐E passes throughout the winter period. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   
26.
正20141456 Chen Juan(Laboratory of High Temperature and High Pressure Study of the Earth’s Interior,Institute of Geochemistry,Chinese Academy of Sciences,Guiyang550002,China);Tang Hongfeng Progress in Analytical Methods of Tungsten Isotope and Experimental Research on Digestion of Whole  相似文献   
27.
应用电感耦合等离子体质谱法(ICP-MS)分析岩石和土壤样品中稀土元素的含量,取样量可低至数毫克级,但200目样品粒度要求分析取样100mg才能保证代表性,导致ICP-MS灵敏度高、取样量小的优势难以得到充分发挥。本文研究了研磨方式、研磨时间、物料比对超细粒度土壤和岩石样品制备的影响,结果表明采用乙醇作为分散剂进行湿法球磨,200目粒度的土壤、岩石样品分别研磨10min和15min,土壤样品的物料比采用物料7g、研磨球500个、分散剂45mL,岩石样品的物料比选取物料5g、研磨球500个、分散剂45mL,细化程度最佳。在此条件下制备的超细粒度土壤标准物质GBW07404、GBW07447的粒径分布D_(95)可低至7.51μm、7.05μm,超细粒度岩石标准物质GBW07104、GBW07121的D_(95)可低至8.42μm、8.30μm。在硝酸-氢氟酸-过氧化氢酸溶体系中微波消解处理超细粒度岩石标准物质GBW07104,取样量减少至5mg,总用酸量减少至0.25mL,消解时间降低为25min,稀土元素的测定值与认定值基本一致,相对标准偏差在1.64%~5.21%之间。该方法用于分析其他超细粒度标准物质(GBW07404、GBW07447和GBW07121)中的稀土元素,相对误差为0.17%~6.60%,满足《地质矿产实验室测试质量管理规范》的一级标准。  相似文献   
28.
Tephra shards for electron probe microanalysis are most efficiently extracted from peat using acid digestion, which removes organic material that hinders density separation methods. However, strong acids are known to alter glass chemical compositions, and several studies have examined how acid digestion affects rhyolitic volcanic glass. The focus on rhyolitic tephra in these studies leaves considerable uncertainty, as the dissolution rates of natural glasses (including tephra) are determined by the chemical composition and surface area/volume ratio, both of which vary in tephra deposits. Here, we use duplicate samples of basaltic, trachydacitic and rhyolitic tephra to examine physical and geochemical alteration following acid digestion. Scanning electron microscope imagery reveals no discernible degradation of glass surfaces, and electron probe microanalysis results from duplicate samples are statistically indistinguishable. These findings suggest the acid digestion protocol for organic peats does not significantly alter glass geochemistry regardless of shard morphologies or geochemical compositions.  相似文献   
29.
建立了微波消解-电感耦合等离子体质谱法测定土壤和沉积物中15种痕量稀土元素的分析方法。研究了溶样试剂、微波消解程序、标准溶液配制、质谱干扰与内标元素对稀土元素测定的影响。加入氢氟酸能有效打开样品,以HNO3-HF-H2O2混合酸溶解样品,稀土元素的溶出率较高。采用模拟土壤、沉积物中稀土元素天然组成比值的校正溶液,对稀土元素间的干扰具有明显的抑制作用。通过测定单个La、Ce、Pr、Nd和Ba的氧化物及氢氧化物产率,计算出等效干扰浓度,进而校正多原子离子干扰。利用103Rh内标校正系统,有效地抑制了分析信号的动态漂移。方法检出限为1.2~7.1 ng/g,精密度(RSD)≤5.3%(n=6),加标回收率为86.1%~110.1%。使用土壤、沉积物标准物质进行验证,测定结果与标准值相符。建立的方法样品处理程序简单快速、线性范围宽、分析重现性好、结果准确,适用于大批量地质样品的分析。  相似文献   
30.
微波消解-原子吸收光谱法测定岩芯中的8种金属元素   总被引:1,自引:1,他引:0  
赵雷  邱会东  原金海 《岩矿测试》2011,30(4):461-464
岩芯分析是油气田开采前期必须开展的必要研究工作。岩芯样品常见金属元素钾(12.30 mg/g)、钠(15.04 mg/g)、铝(28.83 mg/g)、铁(11.13 mg/g)含量较高,且含有大量有机物,文章首次提出以微波消解方式,用浓硝酸和过氧化氢分解有机物,盐酸和氢氟酸处理二氧化硅等无机物,分解稠油油藏岩芯样品效果明显,原子吸收光谱法测定样品中钾、钠、钙、镁、铝、铁、锰、钡8种金属元素的含量。分析结果表明,方法线性相关系数良好(相关系数为0.9949~0.9998),回收率在92.2%~101.6%。建立的微波消解技术无样品损失,操作简单,消解过程节省试剂,减少了环境污染,测定方法准确、可靠,检出限低。  相似文献   
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